Embedded sound hardware is never as good as dedicated sound hardware, especially on a laptop (with a smaller mainboard which has to make more compromises on component bulk, cost, and power consumption).
GL502 audio is probably based on ALC1150 or S1220/S1220A codec parts (or something similar), and probably also has a few ASUS-added filter caps or op-amp chips to provide clean amped headphone output, so it's probably an adequate laptop-integrated audio solution (and it's probably not as good as the best desktop-integrated audio solutions). Quite excellent for gaming and streaming and stuff like that, but I doubt it could output "audiophile" sound quality regardless of how fancy your headphones might be. Also note that ASUS audio software (like all other ASUS software) can be very hit-or-miss.
Any decent external DAC/AMP device will offer much better sound quality. Partly because it just packs more audio hardware components. Partly because it's isolated from the crowded and electrically-noisy laptop internals. External sound devices (especially USB-based ones) also have the advantage of being portable self-contained units which can easily be moved from place to place or machine to machine, easily carried around and plugged into your laptop when needed.
I use an
O2+ODAC - a truly excellent device and I just can't praise its quality, performance, reliability, and simplicity enough. It compares very favourably vs the popular
FiiO Olympus E10K. It even has cleaner sound (in a couple of my machines, anyhow) than Creative's top-end ZxR cards.
The
M-Audio 24/192 Reference DAC is almost as good and it's priced closer to your €100 budget.
Don't be seduced by raw hardware specs (which are essentially over-technical and already beyond the extreme thresholds of human hearing resolution anyhow), and don't be seduced by audiophile jargon (which is essentially non-technical and could just as easily describe the subjective experience of drinking a wine vintage as that of listening to an musical masterpiece) ... what really matters, the only thing that matters, is the actual clarity and fidelity of the sound output.
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