Thanks for the response.
To be clear, lets say my AC5300 is 192.168.2.1
On the 4g modem / router that will be connected to the wan port, lets say I set its IP address to 192.168.0.1 to avoid conflicts. It also has a set address for the Asus router of 192.168.0.60. The DMZ on that device I have set to enabled and 192.168.0.60 (the address of the Asus).
When this is connected to the designated Ethernet Lan port (in the dual wan settings) it works fine. I can also access its protal via 192.168.0.1. However, when connected to the wan port, I cannot access 192.168.0.1 at all. On the Asus network map it shows the error "You have probably stopped the WAN connection manually" and the 4g router doesn't show at all in the device list.
For me it looks like if I could have 2 wan options of Ethernet Lan it would work. But I cannot get either router to have any access whilst connected to the dedicated wan port