Hi,
Do you happen to have a USB pen? there is a option where you can take screenshots of your BIOS, if you posted those here then i could be more clear on the settings you are currently using, are you also sure that you applied plently of decent branded thermal paste to your CPU?
Do you have enough fans inside of your case to move the air flow too? - start first by posting your BIOS settings here if you can please, When the AI Tuner program OC your PC it tend's to not do the full settings unless you use the Extreme option that is in the program but to get a solid OC your better off using the BIOS.
1) Post pictures
2) Ensure your coolers are cleaned up and you did apply good ammount of thermal to your CPU.
3) Vdroop option on your PC adds 'C to your PC, also remember that your ambient room temps come into thought here so you might need to lower your OC if you live in a hot country. I always found 4.4ghz + required too much pump into options that would just add heat.
P.S: On the topic of not knowing what to elimate i can help you there, Hivisman helped me with this and some basic thoughts if you keep updating us here then we can help you. But if you speak good english i would be happy to talk to you through Skype and see if that can be off help to you if you require quicker help. But first start with one setting aka: VDIMMS (ram) set the basic voltages for things you KNOW that are not a issue. also when you set your ram settings declock the CPU back to its standard 3.3ghz and then prime95 it for 12hours if it doesn't have problems you can rule out the options you have just placed in (for now).
Once you have done that, add abit of juice to your pc to go towards 4.2ghz - I use 1.310 voltage in BIOS with a 75% Vdroop and a CPU over-protection of 140%. Prime95 it again and see if it stays stable. Now this is where i helped myself and i simply went back to BIOS and boosted the CPU Multi to x48 and left the voltages at 1.310 and ran the PC while watching temps and saw how fast it crashed and what type of 'C i was getting, this way you can know that it is either: voltages to the CPU or the VRM that needs adjustments.
Simple: Proccess of elimination - the thread i linked you is a hella to get your head around, I don't even fully understand it but after some tinkering and ensuring i keep settings at a certian value and do certian things i can rule out possibilitys that area of my PC was faulty and causing the fault.
P.S: I will say do NOT use offset as it overshoots on the voltages when you are fully loading the CPU it is a nightmare to control. It is a brilliant feature but best used when you are not stressing the PC 100% of the time and you like a low voltage because for example: you leave it idle for several hours a day, but it can overshoot to something like 1.5v when you are fully loaded because you are no longer in control of the Vcore Voltages, setting a fixed voltage will get you better overall temps.
Report your findings back here after you have done this.
PC Specs: Intel 2500k - 4.6GHZ (Overclocked) 7 Stepping CPU.
Corsair Vengance 16GB 4GB Kit @ 1600MHZ 9/9/9/24/2 - now overclocked: 1866 9/10/9/27/2- ATI 6850 GFX - (OC 855mhz/1165) -
Maximus Gene Z/Gen 3 3305 BIOS, Voltages: Ram 1.6 - CPU 1.360 / 75% Vdroop. VCCISO 1.1500.
Antec 300 Case - Sata II 5400 RPM 500GB Master HDD.
RoG Member! And Proud!Lilkka