Well lets see most if not all the G75vw with SSD and 750 Gb, from the factory has the 256gb divided into C: and 😧 the 750gb is partitioned as E: and F:? If you C: is full you might want to uninstall all non important programs and reinstall them on E: Most programs don't care where the are install and load them up won't take that much longer.
If you have some empty space on 😧 you could use something like Minitool Partition Magic, to move some space from 😧 to C:
If your whole 256gb SSD is really completely full then a clean install would be your best move. See Rewbens thread for guides and notesJ Just remember when your reinstalling all your software to use the custom install method and install to E: Program Files rather than C: or 😧