1. I used Aida64 free for a while, but I love it; so, I paid for the basic license. I still love it - haha - there are a lot of voltages you can't see without the full license, as well as HDD temps. OCCT will work the dog out of your machine, as will Aida64.
2. While that Noctua air-cooler is phenomenal, remember that due to the sheer mass of the heat sink, and the fact that heat has to conduct a long way to the fins, temperature spikes will be more extreme. The presence of heat pipes helps (adding an element of convection), but conduction is the least efficient heat-transfer method available to such a system, and it's the primary method by which a PC heat sink works.
You mentioned using a line, and then slightly rotating the heat sink back and forth to settle it. It is my understanding that you only want to help the heat sink settle with rotation using the dot method, as smearing the line of TIM could trap air bubbles more easily. The only way to find out would be to re-paste, using a different method.
So, judging from your temperatures, and what little I know about nominal temperatures for socket 2011 CPUs, it seems that those are pretty normal readings. I don't really use Prime95 anymore - general stress testing: Realbench, and stability testing: Aida64. I've managed to let go of the OCD-driven insanity of trying to get Prime95 to run stable and cool for 10+ hours, since it's not a realistic test of your computer's abilities.
Z