Okay so...
Removed all the kits, then managed to pair up the original kits by serial number, they were sequential. One of them ending on 29, and the last of the kit ending on 32. The other kit ended on something like 40 and going up to 43. I'm assuming these 2 kits came pretty much out the factory at the same time 😛
Anyways I put only one group of them in the DIMM slots marked red (Which the manual shows is proper grouping for a 4-DIMM kit). Boots up fine, Shows 32 gigs in Windows 10, reboot does a QCode 70. Cleared the CMOS, tried again, same result. Tried swapping it out with the other memory kit, reads the memory fine, shows 32gigs in Windows 10. Reboot, and another Qcode 70.
So I don't even know what to try next? Is there a BIOS setting that can skip parts of the "PCH DXE initialization" perhaps?
Thanks for the help so far!