Use the 6 pin PCIe cables (or 6 pin plus 2 pin pig tail) to go from one of the eight pin PCIe / CPU ports on the PSU. The 8 pin ports on the PSU handle both 8 pin cpu cables and 6 pin PCIe cables. If you can, use a 6pin cable that has the 2 pin pigtail on the MB or 3080 ti side. With the pigtail, the cable will be rated for 150 Watts. With only 6 pins, it's 75 Watts
Don't use the CPU cables. It's not worth the chance of frying a $2k piece of equipment. Pin outs are likely different as is the connector.